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简要介绍了苄基型醇催化氢解的方法、催化剂和催化反应的机理。The methods, catalysts and reaction mechanism of the hydrogenolysis of benzyl-type alcohols are reviewed.

肼解还原法是三种方法中产率最高，选择性最好的方法。Hydrozinolysis and hydrogenolysis reduction with high yield and excellent selectivity was the best process among the three.

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以氯乙酸母液和氢气为原料，开发了氢解制氯乙酸的新工艺。A new process of production of chloroacetic acid from mother liquor of chloroacetic acid by hydrogenolysis has been developed.

此外，通过多步骤或利用超临界溶剂、保护基团等也可实现甘油氢解。The hydrogenolysis of glycerol can also be achieved by adopting multiple processes, supercritical solvents or protecting groups.

对甘油催化氢解制取1，2-丙二醇效果最好的是含铜的催化剂。Copper-containing catalysts are the most suitable catalysts for producing 1,2-propanediol through catalytic hydrogenolysis of glycerol.

之后，经引入手性试剂，双键还原，氢解，水解酯基得到目标产物的合成路线。The target molecule was synthesized through using chiral reagent, reduction of double bond, hydrogenolysis and hydrolysis of ester group.

通过采用SEM、X射线衍射、化学元素分析、物理分析等技术，系统地研究了稀土镧对氧化钼氢还原的影响。The effects of rare earth element La during hydrogenolysis were studied by using SEM, X-ray diffraction and chemical and physical analysis.

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甲酸甲酯氢解制甲醇这一步骤的难点在于环境友好的低温高活性铜基催化剂的研制。Hydrogenolysis of methyl formate to methanol was the rate-determining process and was mainly catalyzed by nickel-based or copper-based catalyst system.

反应历程可能为甲醇首先均相催化羰化为甲酸甲酯，然后甲酸甲酯再多相催化氢解为甲醇。The reaction pathway may involve a homogeneous carbonylation of methanol to methyl formate followed by the heterogeneous hydrogenolysis of methyl formate to methanol.

对氧碱木质素进行氢解后，经基比例明显提高，更有利于提高合成高分子材料的反应活性。After hydrogenolysis of wheat alkali-oxygen lignin, the lignin has more hydroxyl, which can easily promote the reaction activity of synthesis of macromolecular material.

在最后一步脱保护基的研究中，我们分别采用了锌粉还原和钯碳氢化两种方法得到最终产品，并对其后处理的方法进行了改进。In the last step, we developed two methods of deprotection employing zinc dust and catalytic hydrogenolysis respectively to give the final product, and improved the work-up as well.