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金属有机化合物是不对称合成中常用的有机试剂。The organometallic compounds are organic reagents in common use for the asymmetric synthesis.
咔唑生物碱的研究进展,生物活性,有机金属合成汇集。Occurrence, Biological Activity, and Convergent Organometallic Synthesis of Carbazole Alkaloids.
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而且有机金属试剂通常需要提前制备,反应条件一般比较苛刻。Moreover, the organometallic reagents needed to be prepared beforehand and the process was rigorous.
二茂铁的发现对金属有机化学的迅速发展起着举足轻重的作用。The discovery of ferrocene plays an important role in quick development of organometallic chemistry.
杂环卡宾已经成为有机金属和无机配位化学中广泛应用的配体。N-Heterocyclic carbenes have become universal ligands in organometallic and inorganic coordination chemistry.
因此,金属配合物应兼具有机和无机发光材料的双重特性。These organometallic complexes should bear characteristics of both organic and inorganic luminescent materials.
有机金属树状分子由于其独特的化学和物理性质,近年来成为研究的热点。Organometallic dendrimers have been attracting much attention due to their unique chemical and physical properties.
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本文介绍了新兴的水溶性有机金属化学及其在两相催化体系中的应用。The aqueous organometallic chemistry and catalysis have become more and more important in the study of "GreedChemistry".
本文简要综述了金属有机化合物在不对称合成中的应用与进展。This article briefly summarized the application and progress of the organometallic compound in the asymmetric synthesis.
用于金属有机化合物中微量钴的测定,结果与理论值相符。This sensitive method has been applied to determine cobalt in organometallic compounds, and the results accord with theoretical values.
在过渡金属配合物中,二茂铁类衍生物是一类具有很好的光电功能的化合物。Among various kinds of transition metal coordinates, Ferrocenyl-containing organometallic complexes possess rich opt-electric properties.
本文主要对我们原先提出的二次极化率矢量模型在金属有机配合物中的适用性进行探讨。This paper explores the suitability of second-order polarizability vector model, which was proposed by us, for the organometallic complexes.
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本文综述了茂型稀土金属有机配合物的研究现状和最新进展。The recent advance of the synthesis and characterization of rare earth organometallic complexes involving cyclopentadienyl types is reviewed.
三价膦化合物作为一种强支持配体与过渡金属能形成稳定的配合物,广泛存在于金属有机化合物中。Trivalent phosphine as a strong ligand can form stable complexes with transition metals, and can be widely found in organometallic compounds.
芳烃和杂环芳烃化合物的碳碳键生成反应一直是有机化学和有机金属化学研究领域中的主要课题。Carbon-carbon bond forming reactions of arenes and heteroarenes are always the major topics in organic chemistry and organometallic chemistry.
本文对近年来外加配体参与的有机金属化合物对亚胺的不对称加成反应,特别是催化合成手性胺类化合物的研究进展作一概述。The recent advances in external ligand-mediated addition of organometallic reagents to imines for the asymmetric synthesis of chiral amines are reviewed.
二茂铁这个实验涉及到一个简单的金属有机化合物-二茂铁的合成,接着再制备二茂铁的衍生物。Ferrocene This experiment involves the synthesis of ferrocene a relatively simple organometallic compound followed by preparation of a ferrocene derivative.
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本课程将具体介绍量子理论,配位化合物,主族化合物,过渡金属化合物和有机金属化合物。This course will introduce quantum theories, coordination compounds, main group compounds, transition metal compounds and organometallic compounds in detail.
一步法主要包括电弧放电法、熔盐电解法、模板法和热解金属有机物法等四种。One-step methods consist of arc-discharge method, electrolytic formation techniques, template-assisted method and pyrolysis of organometallic precursors, etc.
同时表明了向列相有机液晶分子的模型设计同样能很好地指导金属有机液晶分子的设计、合成及介晶性行为的研究。The results show that the model design of nematic organic liquid crystal can also direct the molecular design and synthesis of organometallic liquid crystals.