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本论文研制了一种新型烯烃氢甲酰化催化剂。In this paper, a kind of new catalysts for olefins hydroformylation was studied.

模拟了超临界丙烯氢甲酰反应体系的相行为。The phase behavior of the hydroformylation of propylene in supercritical CO_2 was simulated.

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对环氧乙烷羰基合成1，3-丙二醇的催化体系进行了初步研究。The hydroformylation of 1,3-propanediol from ethylene oxide was summarized by one-step and two-step.

本文综述了采用均相催化剂、均相固载化催化剂以及多相催化剂催化合成丙醛的研究成果。Recent development in hydroformylation of ethene to propanal by catalytic synthesis is introduced in this paper.

对于水溶性差的高碳烯烃，其氢甲酰化反应速度远远低于低碳烯烃。For higher olefin that has poor solubility in water, the hydroformylation reaction rate is much less than short-chain alkenes.

反应温度、空速、压力及物料配比对乙烯转化率和丙醛选择性均产生一定程度的影响。The reaction products of ethylene hydroformylation on the three kinds of catalysts were mainly propanal , ethane and propanol.

研究了水溶性铑膦络合催化剂两相催化1-己烯氢甲酰化反应。The use of the water-soluble Rh-phosphine complexes for catalytic hydroformylation of 1-hexene in two-phase system was studied.

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而通过双键的氢甲酰化反应引入新官能团能为油脂的化工利用提供了一条广阔的道路。Hydroformylation of the olefinic double bonds was n atom economic method th introduce new functional group in the oil compounds.

旋光活性3，4-二甲基磷酸配体及其在不对称羟基化和烯丙基烃化反应中的应用。Optically active 3,4-diazaphospholane ligands and their application in asymmetric hydroformylation and allylic alkylation reactions.

将铑络合物担载于磷钨酸改性的载体上制备了一系列新型催化剂。A series of hydroformylation catalysts were prepared by supporting Rhodium complex in the supporters modified by phosphotungstic acid.

实验结果表明，温控相分离催化体系可很好地催化C6-14直链高碳烯烃氢甲酰化反应。The experiment results indicated that the hydroformylation of C6-14 straight chain higher olefins could well conduct under TPSC system.

以水溶性有机金属配合物为催化剂的两相催化体系是“绿色化学”中发展迅速的前沿研究领域之一。This paper reported the hydroformylation of 1-butene catalyzed by water-soluble rhodium phosphine complex in two-phase catalytic system.

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离子液体作为一种环境友好的溶剂日益为人们所关注。综述了近年来离子液体在氢甲酰化反应中的研究和应用。Ionic liquid can be used as green solvent in homogeneous catalysis. This paper reviews the recent development of hydroformylation of olefin in ionic liquid.

本文综述了对化学工业具有潜在经济价值的油酸甲酯和油醇的氢甲酰化反应的进展，并介绍了反应产物的应用前景。In this text, the developments of hydroformylation of methyl oleate and oleyl alcohol, as well as the reactions and applications of its final products were reviewed.

考察了不同催化剂组合物配方对反应结果的影响，并对反应产物作了较详尽的定性分析。The effect of the various compositions of catalyst on the hydroformylation was also investigated. Furthermore, the reaction products were qualitatively analyzed in detail.

本文综述了烯烃氢甲酰化反应的催化剂从钴配合物到铑配合物和从均相催化体系到两相催化体系的发展过程。The development of the catalysts and the catalytic processes in hydroformylation of olefins was introduced. The catalytic properties of cobalt complexes and rhodium complexes were compared.