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合成一种新的推拉型偶氮化合物并将掺入PMMA中制成光学薄膜器件。The new push-pull azobenzene compound was synthesized and doped into PMMA films.
报道了偶氮苯聚合物薄膜中的斑图形成,横向效应及准晶结构。Pattern formation and transverse effect are reported for azobenzene polymer film.
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偶氮苯及其衍生物的特点在于可逆顺反异构化。Azobenzene and its derivatives are characterized by reversible cis-trans isomerization.
研究了偶氮苯聚合物的光致各向异性光栅与表面光栅。Optically induced anisotropy gratings and surface gratings on azobenzene polymer films are studied.
采用Z扫描技术对一种新的偶氮苯类化合物的三阶非线性光学系数进行了测量。The third order nonlinear optical coefficient of a novel azobenzene compound was investigated by using Z-scan technique.
偶氮苯的光致顺反异构化是许多偶氮类功能材料光响应的基础。The trans-cis photoisomerization of azobenzene is the basis of photo-responsive properties of many azo-functional materials.
偶氮类分子的顺-反结构在光、热的作用下极易发生转变,是引起常温下生色团分子有序取向结构松弛的主要原因。The Cis-Trans photoisomerization and thermal isomerization of azobenzene group was main reason that caused the dipole orientational relaxation.
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采用单光束Z扫描技术对新型光学存储材料偶氮分散红聚合物的薄膜样品进行了测量。A new type of optical storing material, the film sample of azobenzene disperse red polymer is measured by using the single beam Z-scan technique.
利用前向简并四波混频光路,在偶氮苯聚合物薄膜表面制作出六角对称的晶体微结构。A method for laser induced hexagonal symmetry microstructures in an azobenzene containing polymer film is presented based on forward degenerate four-wave mixing.
光致极性和分子结构的变化使偶氮衍生物作为可逆的分子开关器件得以普遍应用。The photoinduced changes in polarity and molecular structure have led to widespread application of azobenzene derivatives as reversible molecular switch devices.
比较了含小分子偶氮苯化合物的高分子薄膜与MAAAB共聚物的光控释放小分子的能力,发现后者具有较强的光控功能。The photoresponsibility of polymer film which contains small molecule of azobenzene compound by mechanical mixing was compared with that of film of MAAAB copolymers.
用偏振紫外光谱研究了两种侧链偶氮聚电解质静电逐层自组装膜中偶氮生色团的初始取向。Orientation of azobenzene units in self assembled multilayer films of two side chain azo polyelectrolytes was investigated by using polarized UV Vis absorption spectroscopy.
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模拟计算的结果表明,在没有外力条件下偶氮苯异构化为平面外绕轴转动的运动。It is found that azobenzene photoisomerization occurs predominantly by an out-of-plane rotation mechanism even under a nontrivial resisting force of several tens of piconewtons.
偶氮苯化合物由于其优良的光学及光致顺反异构性,在光信息材料及生物材料等方面得到了广泛的应用。Substituted azobenzene derivatives are important intermediates in the synthesis of dyes. The interest of azobenzene derivatives originates in a wide rang of potential application.
可以推测,聚合物在衬底表面的这种状态将对偶氮光存储器件的稳定性和工作效率产生不良影响。This geometrical configuration of CAP on the surface of the substrate was proposed to damage the stabilities and efficiency of azobenzene derivatives based optical storage devices.
本篇论文主要是在研究苯亚甲基苯胺与对位烃基偶氮苯衍生物的光化学反应,以及所得到之产物在药性上之应用。This work mainly studies on the photochemical reaction of benzylideneaniline and azobenzene derivatives, we also studies on the pharmaceutical chemistry of the product from our new reaction.
对于有机分子而言,如偶氮苯类染料分子,在光泵浦下会引起聚合物有趣的光学非线性效应,如双折射,双色性,甚至表面形貌改变。Organic molecules, such as azobenzene chromophores, would induce lots of interesting optical nonlinear effects of polymer, for example, birefringence, dichroism, even change of surface relief.
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研究了不同偏振全息模式下基于交联偶氮苯聚合物薄膜的相位光栅的形成机理、衍射效率和偏振特性。The forming mechanism, diffraction efficiency and polarization characteristic of phase gratings written in cross-linked azobenzene copolymer films under different holography modes were studied.