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本文简要综述选择性氟化作用的优点。This paper briefly described the advantages in selective fluorination.
对氟化催化剂在不同气氛下焙烧进行了研究。The fluorination catalysts were investigated to be dried in different atmospheres.
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还可选配液位线装置及上下对吹、在线氟化处理等加工工艺。Side view stripe, head to head blowing, in-machine fluorination processes are an option.
聚乙二醇可作为卤素交换氟化反应有效的相转移催化剂。Polyethylene glycols can be used as effective phase transfer catalyst in halogen exchange fluorination.
研究了利用表面氟化技术制作PMMA聚合物光纤包层的可行性。The feasibility to use surface fluorination technology in the formation of the cladding of PMMA POF is studied.
本文着重阐述了PFTHF的合成方法如电化学氟化法等的研究进展。In this paper the main progress in synthesis methods of PFTHF such as electrochemical fluorination are emphasized.
在离子液体中用氟化钾氟化是一个新的优良氟化方法。It is pointed out by author that fluorination with potassium fluoride in ionic liquids is a good fluorination method.
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卤素交换氟化反应是合成含氟有机化合物的有效方法之一。Nevertheless, the traditional halogen-exchange fluorination needs long time and inevitably companies with serious by-reactions.
氟化催化刑,以及实际生产的工艺流程、工艺条件。A fluorination catalyst for methylene fluoride production by gaseous phase fluorination, and its practical process areintrouduced.
该方法使用了CO_2-激光氟化系统,该系统也可用于从硅酸盐和氧化物中定量的产生O_2。The method utilizes a CO_2-Laser Fluorination system that can also be used to quantitatively generate O_2 from silicates and oxides.
微波加热可以明显促进卤素交换氟化反应的速率,实验结果显示它比常规加热具有更高的选择性和产率。Microwave could promote the halogen-exchange fluorination rate tremendously and gave higher selectivity and yield than traditional heating method.
本文通过对无水氟化氢和三乙胺的混合溶液在一定条件下的电解氟化,制备全氟三乙胺。Perfluorotriethylamine is fabricated through electrochemical fluorination of triethylamine in anhydrous hydrogen fluoride under a certain condition.
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方法以四氯苯酐为原料,经酰亚胺化、氟化、水解得四氟邻苯二甲酸。Methods This preparation of tetrafluorophthalic acid started from tetrachlorophthalic anhydride and underwent amidation, fluorination and hydrolysis.
氟化后活性炭纤维的孔结构和比表面积变小,氮低温吸附等温曲线明显降低。The pore size and specific surface area of ACFs were decreased after fluorination. The adsorption isotherm of nitrogen on ACFs were evidently reduced.
本文着重介绍了气相氟化作用在纺织材料表面改性上的应用现状。Results will be outlined pointing out to what extent the application of gas phase fluorination is suitable for a surface modification of textile materials.
宏观动力学研究表明,常规加热条件下卤素交换氟化反应为一级反应,而在微波加热条件下明显不再是一级反应。Nevertheless, the microwave-promoted fluorination was obviously not a first order reaction yet, which was safe to take it for "non-heat effect" of microwave.
综述了芳香族置换氟化的反应机理与最新研究状况,并展望了其未来发展前景。The reaction mechanism and the latest research status of displacement fluorination of aromatics are summarized, and the development trends are forecasted also.
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选择性地向有机物中引入氟原子越来越受到重视,近年来通过碳碳不饱和键的氟化加成来引入氟原子发展迅速。In this paper, many efficient procedures for introducing fluorine atoms into organic molecules by fluorination addition reactions of unsaturated C-C bonds are reviewed.
从相转移催化剂的种类、原理、反应条件以及它在卤代芳香族化合物氟化反应中的应用等方面对相转移催化剂的作用进行概括和总结。The application of phase transfer catalysis in fluorination of halo-aromatic compounds, mechanism, variety and reaction condition of fluorination are reviewed in this article.
气相催化氟化合成的1,1,1,2-四氟乙烷及其相关副产物组分的气相色谱-红外光谱分析。Analysis of Components of Synthetic 1,1,1,2-Tetrafluoroethane and Its Related By-Products From Vapor Phase Catalytic Fluorination by Gas Chromatography-Fourier Transform Infrared Spectroscopy.